3-Nitro-N-(8-quinol­yl)benzamide

نویسندگان

  • Gang Lei
  • Lin-Hai Jing
  • Li Zhou
چکیده

The title compound, C(16)H(11)N(3)O(3), crystallizes with two independent mol-ecules which are almost identical to each other in the asymmetric unit. The dihedral angle between the quinoline ring system and the nitro-benzene ring is 51.04 (9)° in one of the mol-ecules and 48.91 (9)° in the other. The crystal packing is stabilized by C-H⋯O hydrogen bonds and π-π inter-actions, with a centroid-centroid distance of 3.6010 (15) Å.

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منابع مشابه

4-Nitro-N-(8-quinol­yl)benzamide

In the title compound, C(16)H(11)N(3)O(3), the amide group is twisted away from the plane of the quinoline benzene ring by 3.93 (5)°, but is twisted away from the nitro-benzene ring by 22.68 (4)°. A weak intra-molecular C-H⋯O hydrogen bond is observed. In the crystal structure, mol-ecules are linked into a chain along the a axis by inter-molecular C-H⋯O hydrogen bonds.

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2-Nitro-N-(8-quinolyl)benzamide

In the title compound, C(16)H(11)N(3)O(3), the amide group is twisted away from the quinoline ring system and nitro-benzene ring by 8.02 (1)° and 54.92 (1)°, respectively. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds, and π-π inter-actions between the quinoline ring systems of inversion-related mol-ecules, with a centroid-centroid distance of 3.4802 (13) Å.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008